Production of Nanostructured metal catalysts
Nanostructured metal powders
Hetero Nanostructured metal
Nanostructured metals
Catalysis by Small Metal Clusters
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Co (0) – Toluene in toluene solution (Stabilized by 2-butyne) Con microclusters, (n ≤ 10) as evidenced by EPR Active in the cyclococyclization of alkynes and nitriles;it has been proved successful even in hydroformylation reaction. Suitable for the deposition of activated Co particles, ranging 2 – 3 nm in diameter, on C or solid oxide supports. J. Mol. Catal., 56 (1989) 133. Rhodium – Mesitylene in mesitylene solution Rhodium – THF in THF solution (Stabilized by trioctylamine (TOA)) Rhn nanoclusters ranging 0.5 – 1 nm in diameter Active in hydrogenation, hydroformylation and hydrosilylation reactions Excellent precursors for the deposition of activated Rh particles,ranging 1 – 2 nm in diameter, on C or solid oxide supports. J. Organomet. Chem., 487 (1995) 41 ; Sinth. Methods Organomet. and Inorg. Chemistry, Catalysis, Brauer, Herrmann, Vol.10, 64-71 (2002). |
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Homogeneous CatalystsMetal catalysts presently available
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| Advanced nanostructured metal powders Catalysts by Small Metal Clusters,Hydrogenation catalysis,Bimetallic catalytic systems,Very active and selective New generation catalysts, Homogeneous Heterogeneous Oxidation Polymerization catalysts, Production of Hetero Nanostructured metals catalysts, Metal vapors technology technique |
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Co (0) – Toluene in toluene solution (Stabilized by 2-butyne) Con microclusters, (n ≤ 10) as evidenced by EPR Active in the cyclococyclization of alkynes and nitriles;it has been proved successful even in hydroformylation reaction. Suitable for the deposition of activated Co particles, ranging 2 – 3 nm in diameter, on C or solid oxide supports. J. Mol. Catal., 56 (1989) 133. Rhodium – Mesitylene in mesitylene solution Rhodium – THF in THF solution (Stabilized by trioctylamine (TOA)) Rhn nanoclusters ranging 0.5 – 1 nm in diameter Active in hydrogenation, hydroformylation and hydrosilylation reactions Excellent precursors for the deposition of activated Rh particles,ranging 1 – 2 nm in diameter, on C or solid oxide supports. J. Organomet. Chem., 487 (1995) 41 ; Sinth. Methods Organomet. and Inorg. Chemistry, Catalysis, Brauer, Herrmann, Vol.10, 64-71 (2002). An example of the catalytic activity and selectivity of homogeneous catalysts: Idrosilylation of vinyl compounds with a Pt-mesitylene solution obtained via MVS technique. In analogous conditions a Pt “Karstedt” catalyst does not catalyse the reaction.
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