Carbon-Carbon coupling reactions catalysts Hydrogenation catalysts

Rh/C

Excellent catalysts for hydrogenation, hydrosilylation, silylformilation reactions; they are largely more active than analogous commercial


Particles size distribution of a commercial Rh/g-Al₂O₃ sample		Particles size distribution of a MVS Rh/g-Al₂O₃ sample

Rhodium: metal particles ranging 1-2 nm in diameter

Rh/g-Al₂O₃

Supported Catalysts

Advanced nanostructured metal powders Catalysts by Small Metal Clusters, Production of Hetero Nanostructured metals catalysts, Homogeneous Heterogeneous Oxidation Polymerization catalysts,Hydrogenation catalysis, Metal vapors technology technique,Very active and selective New generation catalysts,Bimetallic catalytic systems

Alkynes Silylformylation

Silylformylation reaction of 1-hexine with a commercial Rh/g-Al₂O₃ 5 w/w % and with an analogous system prepared via M V S technique

Synthesis and Methodologies in Inorganic Chemistry, L. Armalao, D. Barreca, S. Daolio, E. Tondello, P. A. Vigato, Eds. 2001, vol. 9, pp. 43-51

Particles size distribution of a Pd/C sample

Pd/PDMP

Excellent catalysts for Heck reactions, without valuable leaching of Pd

Particles size distribution of a Pd/PDMP sample

(PDMP = polydimethylphosphazene)

Applicative Aspects Polyorganophosphazenes, M. Gleria, R. De Jaeger, Eds. Nova Science Publ., New York (2004) pp.255-265

Gold: particle size distribution raging 4 nm in diameter

Au/g-Al₂O₃

Au/C

Valuable catalysts for hydrosilylation reactions

Particles size distribution of Au/C 1 % w/w sample

J. Organomet.Chem., 690 (2005) 1063

Pd/g-Al₂O₃

Pd/C

Very active Hydrogenation catalysts

Cobalt: metal particles ranging 2.5 nm in diameter

Co/g-Al₂O₃

Co/C

Very active in Fischer-Tropsch reaction

Examples of the activity of supported catalysts prepared via MVS technique

Arene Hydrogenation


Hydrogenation reaction of aromatic compounds with a commercial Rh/g-Al₂O₃ 5 w/w % and with an analogous system prepared via M V S technique

Ruthenium: metal particles ranging 2.4 nm in diameter

Ru/g-Al₂O₃

Ru/C

Very active arene hydrogenation catalysts

J. Organomet.Chem., 289 (2004) 639

J. Oganomet. Chem., 681 (2003) 37

Palladium: metal particles ranging 1-2 nm in Pd/g-Al₂O₃ and Pd/C samples and 3-4 nm in Pd/PDMP catalysts

Oxidation catalysts

Carbon-Carbon coupling reactions catalysts Production of Hetero Nanostructured metals catalysts,Advanced nanostructured metal powders Catalysts by Small Metal Clusters,Hydrogenation catalysis, Metal vapors technology technique,Bimetallic catalytic systems, Homogeneous Heterogeneous Oxidation Polymerization catalysts,Very active and selective New generation catalysts

Oxidation catalysts,Bimetallic catalytic systems,New generation catalysts,Catalysis by Small Metal Clusters,Nanostructured Metal,Heterogeneous catalysis,Metal vapors technique,Production of Nanostructured metal catalysts,Very active and selective catalysts,Nanostructured metal catalysts,Advanced Catalysts, Nanostructured metals,Metal vapors technology,Homogeneous catalysis,Nanostructured metal powders,Analyzing of Materials,Carbon-Carbon coupling reactions catalysts,Advanced nanostructured metal,Hetero Nanostructured metal,Hydrogenation catalysts,Polymerization catalysts